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1) Central metal ion : The positively charged metal ion which accepts electron pairs during formation of coordinate bond is called as metal ion. It is Lewis acid. For example, Co3+ , Ni2+ etc act as Central metal ions in formation of complexes. 

2) Ligand : The anion or neutral molecule, which donates electron pair during formation of complexes, is called as ligand. It is Lewis base. For example, anions like Cl-, CN- etc and neutral molecules like NH3, H2O etc act as ligands. 

Ligand can form one or more bonds with Sam metal ion . On the basis of this, the ligands are classified into various types. 

 

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